Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 1 / 20 Date of issuing: January 01, 2020 SAFETY DATA SHEET 1. Identification Product identifier : Reference No : Information on company Company name : Valve Regulated Lead-acid Battery (VRLA Battery) Hitachi Chemical Energy Technology Co., Ltd. Relevant dept. : Design Dept. Address : No.16 Gongye W. Rd., Erzhen Village, Guantian District, Tainan City 72048, Taiwan (R.O.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 2 / 20 Date of issuing: January 01, 2020 Precautionary Statements : Prevention ; Response ; Storage ; Disposal ; Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Do not breathe dusts or mists.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 3 / 20 Date of issuing: January 01, 2020 If on skin : If in eyes : If swallowed : Most important symptoms/effects, acute and delayed : Protection for first-aiders : Special note to physician : Get medical advice/attention. (Lead, lead dioxide, lead sulfate) Wash skin with plenty of water and soap. If skin irritation occurs, get medical advice/attention.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 4 / 20 Date of issuing: January 01, 2020 Specific fire fighting method : Protection for fire-fighters : There is a possibility of explosion of the product by heat. May form explosive air/gas mixture during charging. There is a possibility of hydrogen emission and explosion during charging. Cut off the power in case of connection/energizing the product into the device, if can be coped with safely.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 5 / 20 Date of issuing: January 01, 2020 Local exhaust/general ventilation ; Cautions for Safety Handling ; Storage : Technical measures ; Storage condition ; Work in a well-ventilated place and provide local exhaust or general ventilation as necessary. Do not use fire near the product. Do not dismantle or modify the product. Do not do short-circuit between the terminals.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 6 / 20 Date of issuing: January 01, 2020 Eye protection ; Wear protective glasses, goggle type safety glasses and the like. Wear protective clothing, protective apron and the like as necessary. Do not eat, drink or smoke when handling. Wash hands thoroughly after handling. Protective equipment shall be inspected regularly according to the protective equipment checklist.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 7 / 20 Date of issuing: January 01, 2020 Hazardous reactivity : Conditions to avoid : Incompatible materials : Hazardous decomposition products : Other information (lead dioxide/ lead sulfate) It is considered to be stable under normal handling and storage. (dilute sulfuric acid) At first, vapor is generated by heating, and generate sulfuric acid vapors if continue to heat.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 8 / 20 Date of issuing: January 01, 2020 11. Toxicological Information Indicate the information for each of components of lead acid battery as below.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 10 / 20 Date of issuing: January 01, 2020 Serious eye damage/eye irritation : Respiratory or skin sensitization : Germ cell mutagenicity : Carcinogenicity : Reproductive toxicity : Specific target organ toxicity (single exposure, repeated exposure) : corrosion/irritation.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 12 / 20 Date of issuing: January 01, 2020 Carcinogenicity : Reproductive toxicity : Specific target organ toxicity (single exposure) : necessarily matched results have been obtained, there is also the positive result in chromosome analysis using peripheral blood of workers who received the occupational exposure of lead.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 13 / 20 Date of issuing: January 01, 2020 Specific target organ toxicity (repeated exposure) : system. There is the description that the hemoglobin synthesis inhibition and small blood cell anemia and hypochromic anemia due to shortened of red blood cell life are caused by δ-aminolevulinic acid and heme synthesis enzyme are inhibited.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 15 / 20 Date of issuing: January 01, 2020 Germ cell mutagenicity : Carcinogenicity : Reproductive toxicity : Specific target organ toxicity (single exposure) : Specific target organ toxicity (repeated exposure) : results in sulfate of zinc.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 16 / 20 Date of issuing: January 01, 2020 Aspiration hazard : Others : inhalation exposure test using the guinea pigs, respiratory and lung disorder, such as nasal-septum dropsy, pulmonary emphysema, atelectasis, hyperemia, dropsy, bleeding and thrombosis of bronchioles are observed at the concentration range of guidance value of Category 1 of GHS Specific target organ toxicity (repeated exposure).
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 17 / 20 Date of issuing: January 01, 2020 Mobility in soil : Hazardous to the ozone layer : ○Dilute sulfuric acid (electrolyte) Ecotoxicity : Persistence/degradability : Bioaccumulation : Mobility in soil : Hazardous to the ozone layer : No information. Not contain ingredients listed in the Annex of the Montreal Protocol.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 18 / 20 Date of issuing: January 01, 2020 [Special Provision A67].Our seal lead-acid batteries can be safely transported on deck, or under deck stored on either a passenger or cargo vessel as result of passing the Vibration and Pressure Differential Tests as described in the IMDG regulations(Special Provision 238).
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 19 / 20 Date of issuing: January 01, 2020 Section 304 CERCLA Hazardous Substances ; Section 311/312 Hazard Categorization ; Section 313 EPCRA Toxic Substances ; Clean Air Act : Clean Water Act : STATE REGULATIONS (US) : Proposition 65 ; 1,000 lbs. Reportable Quantity (RQ) for spilled 100% sulfuric acid under CERCLA (Superfund) and EPCRA (Emergency Planning and Community Right to Know Act) is 1,000 lbs.
Reference No: Valve Regulated Lead-acid Battery Hitachi Chemical Energy Technology Co.,Ltd. Page 20 / 20 Date of issuing: January 01, 2020 16. Other Information Reference: Globally Harmonized System of classification and labelling of chemicals, (5th ed., 2013), UN JIS Z 7253:2012 1) NITE GHS classification data. 2) ECHA Home page (http://echa.europa.eu/information-on-chemicals) 3) NITE CHRIP (http://www.safe.nite.go.jp/japan/sougou/view/SystemTop_jp.